Solvent Effect on Sulfur Ylide Mediated Epoxidation Reaction

Hee-Yoon Lee; Imhyuck Bae; Kyung-Hyun Min

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Solvent Effect on Sulfur Ylide Mediated Epoxidation Reaction

机译：溶剂对硫叶立德介导的环氧化反应的影响

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摘要

The solvent effect on sulfur ylide mediated epoxidation reaction was studied systematically.While higher trans/cis ratio of the epoxide was obtained in the more polar solvent,protic solvent produced the lower trans/ cis ratio than any aprotic solvent.

机译：较系统地研究了溶剂对叶立德硫醇介导的环氧化反应的影响。虽然在极性更大的溶剂中环氧化物的反式/顺式比更高，但质子溶剂的反式/顺式比值低于任何非质子溶剂。

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《Bulletin of the Korean Chemical Society》 |2007年第11期|共5页
作者
Hee-Yoon Lee; Imhyuck Bae; Kyung-Hyun Min;
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正文语种 eng
中图分类化学工业;
关键词
Sulfur ylide; Epoxidation; Solvent effect; Stereoselectivity;

机译：内含硫;环氧化;溶剂效应;立体选择性;

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专利

1. Solvent Effect on Sulfur Ylide Mediated Epoxidation Reaction [J] . Hee-Yoon Lee, Imhyuck Bae, Kyung-Hyun Min Bulletin of the Korean Chemical Society . 2007,第11期

机译：溶剂对硫叶立德介导的环氧化反应的影响
2. Sulfur Ylide Mediated Three-Component Aziridination and Epoxidation Reactions Using Vinyl Sulfonium Salts [J] . Christoforos G. Kokotos, Eoghan M. McGartigle, Varinder K. Aggarwal Synlett . 2008,第14期

机译：乙烯基lide盐对硫酰内酯介导的三组分氮氧化和环氧化反应
3. Sulfur Ylide Mediated Three-Component Aziridination and Epoxidation Reactions Using Vinyl Sulfonium Salts [J] . Christoforos G. Kokotos, Eoghan M. McGartigle, Varinder K. Aggarwal Synlett . 2008,第14期

机译：乙烯基lide盐对硫酰内酯介导的三组分氮氧化和环氧化反应
4. Solvent-Free Stereoselective Synthesis of Chalcones via Wittig Reaction of Arsonium Ylide by Grinding [C] . Wang Changqing International Conference on Energy, Environment and Sustainable Development . 2014

机译：通过研磨通过芳烃ylide的Wittig反应无溶剂立体选择性合成Chalcone
5. Dynamics of the Solvent Exchange Reaction of Weakly Bound Organic Solvents to Group 6 Transition Metal Carbonyls and the Molybdenum Hexacarbonyl Mediated Pauson-Khand Reaction [D] . Gates, Richard J. 2012

机译：弱结合有机溶剂与第6组过渡金属羰基的溶剂交换反应动力学和六羰基钼介导的Pauson-Khand反应
6. Towards a General Understanding of Carbonyl‐Stabilised Ammonium Ylide‐Mediated Epoxidation Reactions [O] . Johanna Novacek, Lukas Roiser, Katharina Zielke, -1

机译：对羰基稳定化的铵化铵介导的环氧化反应的一般理解
7. Practical and Highly Selective Sulfur Ylide-Mediated Asymmetric Epoxidations and Aziridinations Using a Cheap and Readily Available Chiral Sulfide: Extensive Studies To Map Out Scope, Limitations, and Rationalization of Diastereo- and Enantioselectivities [O] . Illa Soler, Ona, Namutebi, Mariam, Saha, Chandreyee, 2013

机译：实用和高度选择性的硫叶立德介导的不对称环氧化和叠氮化使用廉价和容易获得的手性硫化物：广泛的研究以画出范围，局限性和非对映和对映选择性的合理化

Solvent Effect on Sulfur Ylide Mediated Epoxidation Reaction

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