Transition Metal Cluster Chalcogenide Ligated by Multiple Redox Active Organometallic Centers:[Ni_6(mu_3-Se)_2(mu_4-Se)_3(dppf)_3]Br_2 and Its Electrocatalysis

摘要

One of the current trends in molecular material science concerns the preparation and the study of materials combining several physical properties in a synergistic way.Organic/inorganic hybrids,in which organic- or organo-metallic- moieties having a special physicochemical property are incorporated into a transition-metal cluster,may exhibit certain coupling phenomena between the d-electrons of inorganic transition-metal networks and the mobile pi-electrons of the organic conjugated networks.