CH_4 inclasions in orogenic harzbargite: Evidence for redaced slab flaids and implication for redox melting in mantle wedge

摘要

Fluids released from the subducting oceanic lithosphere are generally accepted to cause mantle wedge peridotite melting that produces arc magmas. These fluids have long been considered to be dominated by highly oxidized H2_O and CO_2 as inferred from erupted arc lavas. This inference is also consistent with the geochemistry of peridotite xenoliths in some arc basalts. However, the exact nature of these fluids in the mantle wedge melting region is unknown. Here, we report observa_tions of abundant СН4 + C + H2 fluid inclusions in olivine of a fresh orogenic harzburgite in the Early Paleozoic Qilian suture zone in Northwest China. The petrotectonic association suggests that this harzburgite body represents a remnant of a Paleo_zoic mantle wedge exhumed subsequently in response to the tectonic collision. The mineralogy, mineral compositions and bulk-rock trace element systematics of the harzburgite corroborate further that the harzburgite represents a high-degree melt_ing residue in a mantle wedge environment. Furthermore, existing and new C, He, Ne and Ar isotopes of these fluid inclusions are consistent with their being of shallow (i.e., crustal vs. deep mantle) origin, likely released from serpentinized peridotites and sediments of the subducting oceanic lithosphere. These observations, if common to subduction systems, provide addi_tional perspectives on mantle wedge melting and subduction-zone magmatism. That is, mantle wedge melting may in some cases be triggered by redox reactions; the highly reduced ('AFMQ-5, i.e., 5logunits below the fayalite_magnetite_quartz oxygen fugacity buffer) СН4-rich fluids released from the subducting slab interact with the relatively oxidized (_AFМQ-1) mantle wedge peridotite, producing H2_O and CO2 that then lowers the solidus and incites partial melting for arc magmatism. The significance of slab-component contribution to the geochemistry of arc magmatism would depend on elemental selection and solubility in highly reduced fluids, for which experimental data are needed. We do not advocate the above to be the pri_mary mechanism of arc magmatism, but we do suggest that the observed highly reduced fluids are present in mantle wedge peridotites and their potential roles in arc magmatism need attention.