Oxygen isotopic studies of the interaction between xenoliths and mafic magma, Voisey's Bay Intrusion, Labrador, Canada

摘要

Sulfide mineralization in the Voisey's Bay Intrusion, Labrador, Canada, is closely associated with country rock xenoliths that have extensively reacted with basaltic magma. In order to better understand the processes that control the assimilation of country rocks by mafic magma, a detailed study of oxygen isotope systematics related to magma-country rock interaction in the Voisey's Bay area was undertaken. Protracted interaction of the xenoliths with magma produced refractory mineral assemblages in the xenoliths (2-10 cm in diameter) composed of Ca-rich plagioclase, corundum, hercynite, and minor magnetite. Overgrowth rims of plagioclase and biotite that surround most xenoliths separate the restites from the enclosing igneous matrix. The delta O-18 values of minerals from regionally metamorphosed pelitic and quartzofeldspathic protoliths are: plagioclase (8.7-12.3 parts per thousand), orthoclase (9.5-9.8 parts per thousand), biotite (5.2-8.7 parts per thousand), garnet (8.3-10.8 parts per thousand), pyroxene (8.0-10.1 parts per thousand), and quartz (9.6-14.0). The delta O-18 values of minerals from the hornfels in the contact aureole of the intrusion are consistent with modeling which indicates that as a result of essentially closed system contact metamorphism oxygen isotope values should differ only slightly from those of the protoliths. Hercynite, plagioclase, and corundum separates from the xenoliths have delta O-18 values that vary from 2.9 parts per thousand to 10.5 parts per thousand, 5.6 parts per thousand to 10.9 parts per thousand, and 2.0 parts per thousand to 6.8 parts per thousand, respectively. Although a siliceous O-18-enriched melt has been lost from the xenoliths, corundum, and feldspar 6180 values are significantly lower than expected through melt loss alone. The relatively low delta O-18 values of minerals from the xenoliths may be a function of incomplete isotopic exchange with surrounding mafic magma which had a delta O-18 value of similar to 5.5 parts per thousand to 6.0 parts per thousand. The high-O-18 melt that was released from the xenoliths is partially recorded in the plagioclase overgrowth on the margin of the xenoliths (delta O-18 values from 6.2 parts per thousand to 10.7 parts per thousand), and in hercynite that replaced corundum. However, mass balance calculations indicate that a portion of the partial melt must have been transferred to magma that was moving through the conduit system. delta O-18 and delta D values of biotite surrounding the plagioclase overgrowth range from 5.0 parts per thousand to 6.2 parts per thousand and -58 parts per thousand to -80 parts per thousand, respectively. These data suggest that the outermost rim associated with many xenoliths has closely approached isotopic equilibrium with uncontaminated mafic magma. The current gabbroic to troctolitic matrix of the xenoliths shows no evidence for contamination by the high-O-18 partial melt from the xenoliths. The feldspar and biotite overgrowths on the xenoliths that formed after the motion of the xenoliths relative to the magma had stopped prevented further isotopic exchange between the xenoliths and final magma. The minerals within the xenoliths are not in oxygen isotopic equilibrium with each other, due in part to rapid thermal equilibration, partial melting, and partial exchange with flow through magma. (c) 2006 Elsevier Inc. All rights reserved.