Investigation of double-diffusive convection during the solidification of a binary mixture (NH4Cl-H2O) in a trapezoidal cavity

摘要

The solidification of binary mixture (NH4Cl-H2O) inside a trapezoidal cavity is investigated experimentally in this study. The effect of the initial concentration of ammonium chloride (0-19.8%) and boundary temperatures (-30 to 0 degrees C) on the solidification process was investigated. Particle image velocimetry (PIV) technique was used for the visualization of the dynamic field in the melt. Thirty-two thermocouples were used to monitor the temperature distribution inside the cavity and on the cooling walls. The convective flow field, the temperature distribution, the frozen layer thickness and the moving solid/liquid interface were obtained for different initial concentrations of ammonium chloride and various boundary temperatures. The results obtained in the course of this study reveal that: (1) the process of solidification is slower with an increase in initial concentration levels of the binary solution: as the concentration increases, the time needed to get the same thickness of frozen layer increases; (2) an increase in the initial concentration of ammonium chloride solution reduce significantly the temperature in the me and (3) the initial concentration play a significant role in the evolution of convection flow patterns.