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Thermoluminescence behaviour of GdAlO3:Yb3+ under gamma exposure

机译:伽马射线照射下GdAlO3:Yb3+的热释光行为

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摘要

Thermoluminescence behaviour of Yb3+ doped GdAlO3 was studied for solution combustion synthesised phosphor. The TL glow curve was recorded under gamma radiation. The Tl glow curve was recorded for various heating rate for constant 0.25 kGy gamma radiation to optimize the heating rate. The optimized heating rate was obtained at 4 A degrees C s(-1). The effect of gamma dose on TL behaviour of the phosphor was studied by recording the TL for different gamma radiation dose from 0.25 to 1.25 kGy. For lower gamma dose the TL glow peak consists kinked peak with T-m at 397 and 432 K. As the gamma dose increases the T-m at lower temperature side vanished and the TL glow curve consists only one peak of higher temperature i.e. 432 K. To explain the variation in TL behaviour with variable gamma dose the TL glow curve for different gamma dose was analysed by using computerized glow curve deconvolution method. The kinetic parameters were calculated for all the deconvoluted peaks by using Chen's peak shape method. Activation energy for higher temperature peak is more than lower temperature peak due to deeper and shallow traps respectively.
机译:研究了Yb3+掺杂GdAlO3在溶液燃烧合成荧光粉中的热释光行为.TL辉光曲线是在伽马辐射下记录的。在恒定的0.25 kGy伽马辐射下,记录了不同加热速率的Tl辉光曲线,以优化加热速率。在4 A °C s(-1)下获得优化的加热速率。通过记录0.25至1.25 kGy不同伽马辐射剂量下的TL,研究了伽马剂量对荧光粉TL行为的影响。对于较低的伽马剂量,TL辉光峰由扭结峰组成,T-m为397和432 K。随着伽马剂量的增加,低温侧的T-m消失,TL辉光曲线仅包含一个较高温度的峰,即432 K。为了解释不同伽马剂量下TL行为的变化,采用计算机化辉光曲线反卷积方法分析了不同伽马剂量下的TL辉光曲线。采用Chen峰形法计算了所有去卷积峰的动力学参数。由于陷阱较深和较浅,较高温度峰值的活化能大于较低温度峰值。

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