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首页> 外文期刊>Erdol Erdgas Kohle >Mechanism of Conversion of Heavy Aromatic Feedstocks into Petroleum Pitches by Thermal Soaking Reactions
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Mechanism of Conversion of Heavy Aromatic Feedstocks into Petroleum Pitches by Thermal Soaking Reactions

机译:热浸反应将重质芳烃原料转化为石油沥青的机理

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摘要

Pitch — a complex mixture of polynuclear aromatic hydrocarbons (PAHs) - is a versatile precursor for making a variety of advanced carbon materials such as carbon fibers, carbon composites, anti-earthquake components, lubricants, battery anodes etc. Conventionally, pitches are prepared by thermal treatment of aromatic rich feedstocks. Different types of inorganic and organic catalyst are reported in the literature for promoting the polymerization and condensation reactions viz; Organic peroxides, Lewis acids (AlCl3 & FeCl3) and super acids (HF-BF3) etc. The aim of the present paper is to review and get a deeper insight into the chemistry and various mechanisms of conversion of aromatic feed stocks into petroleum base impregnating type quality pitches with or without catalyst, considering the effect of catalyst on thermal treatment, duration, reusability of catalyst and final pitch quality using lab/experimental data. The pitch prepared by above-mentioned processes compares well in properties with Ashland Petroleum Company's A-240pitch, a widely used impregnating pitch in graphite electrodes plants. These pitches also have good handling, transportation and storage properties.
机译:沥青-一种多核芳香烃(PAHs)的复杂混合物-是一种通用的前体,可用于制造各种高级碳材料,例如碳纤维,碳复合材料,抗震组分,润滑剂,电池负极等。富芳烃原料的热处理。在文献中报道了不同类型的无机和有机催化剂,以促进聚合和缩合反应。有机过氧化物,路易斯酸(AlCl3和FeCl3)和超强酸(HF-BF3)等。本文的目的是对芳族原料转化为石油基浸渍剂的化学方法和各种机理进行综述,并对其有更深入的了解。使用或不使用催化剂时,使用实验室/实验数据考虑催化剂对热处理,持续时间,催化剂的可重复使用性和最终沥青质量的影响,确定类型是否具有催化剂的沥青质量。通过上述方法制备的沥青在性能上与亚什兰石油公司的A-240pitch相当,后者是石墨电极工厂中广泛使用的浸渍沥青。这些沥青还具有良好的处理,运输和储存性能。

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