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Effects of an embedding bulk fluid on phase separation dynamics in a thin liquid film

机译:包埋体液对薄膜中相分离动力学的影响

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Using dissipative-particle-dynamics simulations, we study the effects of an embedding bulk fluid on the phase separation dynamics in a thin planar liquid film. The domain growth exponent is altered from 2D to 3D behavior upon the addition of a bulk fluid, even though the phase separation occurs in 2D geometry. Correlated diffusion measurements in the film show that the presence of bulk fluid changes the nature of the longitudinal coupling diffusion coefficient from logarithmic to algebraic dependence of 1/s, where s is the distance between the two particles. This result, along with the scaling exponents, suggests that the phase separation takes place through the Brownian coagulation process.
机译:使用耗散粒子动力学模拟,我们研究了在平面液体薄膜中嵌入大体积流体对相分离动力学的影响。即使在2D几何形状中发生相分离,添加本体流体后,畴生长指数也会从2D行为更改为3D行为。薄膜中相关的扩散测量结果表明,大量流体的存在改变了纵向耦合扩散系数的性质,从对数依赖性变为1 / s的代数依赖性,其中s是两个粒子之间的距离。该结果以及结垢指数表明,相分离是通过布朗尼凝聚过程进行的。

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