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Aluminium, cooper and ironsalts doped TiO2films abilities in self-cleaning application

机译:铝,铜和铁盐掺杂的TiO2膜具有自清洁功能

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Three types of metals, Al, Cu and Fe.doped TiO2 thin filmsat deferent concentrations were prepared via sol-gel method achieves using dip-coating technique. All the samples were undergone to calcination in a furnace at (450°C) with temperature rate of 20°C/min for three hours. XRDtest show anatase crystal phase for all films. The absorption spectra were adopted for calculation the band gap. Noticeable UV to visible red shifts was recordedin Fe-doped TiO2samples (absorption edge reach 418.92 nm) .while minor shift were observed in both Al-doped TiO2 and Cu-doped TiO2 samples. Systematic absorption edges shifting with concentration dependence were realized for all adopted samples. Self-cleaning capability of the prepared samples were examinedinterrelated to the hydrophiliciry using contact angle measurements.
机译:采用浸涂技术,通过溶胶-凝胶法制备了不同浓度的三种类型的铝,铜和铁掺杂的TiO2薄膜。将所有样品在(450℃)的炉中以20℃/ min的速率进行煅烧3小时。 XRDtest显示所有膜的锐钛矿晶相。采用吸收光谱计算带隙。在掺铁的TiO2样品中(吸收边缘达到418.92 nm)记录到明显的紫外到可见红移。而在掺铝的TiO2和掺铜的TiO2样品中均观察到较小的偏移。对于所有采用的样品,均实现了与浓度相关的系统吸收边缘移动。使用接触角测量法检查了所制备样品的自清洁能力与亲水性相关。

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