Activation energy for diffusion of helium in water-saturated, compacted Na-montmorillonite

摘要

It is important to clarify the migration behavior of hydrogen gas dissolved in water-saturated, compacted bentonite, which is a promising material for geologic disposal of high-level waste and TRU waste disposal. The diffusion coefficients of helium, which can be detected under extremely low background conditions, in water-saturated, compacted Na-montmorillonite were determined as a function of temperature by a transient diffusion method. The activation energies for diffusion of helium were then obtained. The activation energies were from 6.9 +- 4.8 to 19 +- 2.8 kJ mol~(-1) and were regarded to be independent of dry density. The activation energies of helium in water-saturated Na-montmorillonite were roughly equal to those in bulk water, 14.9 kJ mol~(-1), and in ice, from 11 to 13 kJ mol~(-1). It is possible that helium diffuses not only in pore water but also in interlayer water.