Magnetothermal study of nanocrystalline particle formation in amorphous electroless Ni-P and Ni-Me-P alloys

摘要

The microstructure of amorphous Ni-P and Ni-Me-P materials and especially its change during the heat treatment is of great importance for their magnetic, mechanical and corrosion behavior. A new magnetic phase analysis method (magnetothermal) is presented that reveals the precipitation of nanoparticles with strong magnetic properties during phase transformation upon heat treatment. It is applied to electroless Ni-P, Ni-Cu-P and Ni-Sn-P amorphous alloys. The results acquired by this method are compared with data obtained by differential scanning calorimetry, as well as by microhardness measurements using identical heat treatment in all three cases. Due to the high sensitivity of the magnetothermal method a more detailed picture of the precipitation processes in Ni-P alloys is obtained and the new information is discussed. Magnetothermal measurements reveal several stages of precipitation of a phase with strong magnetic properties. This phase is Ni in the Ni-P alloy, and Ni(Me) solid solution in the Ni-Me-P alloys. Though Sn has a stronger effect on the Ni magnetization, Cu is more effective in preventing the appearance of high magnetization in a thermally treated Ni-Cu-P alloy. This is due to Cu incorporation in Ni particles in a quantity above four times larger than Sn.