Influence of surface preparation on performance of chromate conversion coatings on Alclad 2024 aluminium alloy Part I: Nucleation and growth

摘要

The microstructure and morphology of the surface of aluminium alloys strongly affect the nucleation, growth, and p!.otective properties of chromate conversion coatings. Samples of AA 2024- T3 cladded with AA 1230 were pretreated with two different procedures before they underwent a chromating process, which consisted of dipping in a commercial Alodine 1200 solution. In one procedure, an extra step, consisting of immersion in nitric-hydrofluoric acid solution for 30 s (desmutting bath), was carried out after immersion in sulfuric -phosphoric acid solution (acid pickling bath). Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM) and electrochemical investigations highlighted the fact that this extra step in the pretreatment route gave rise to a more etched, but less r~active surface, due to the removal of a large amount ofcithodic sites, mainly related to AI-Fe-Si precipitates present in the clad layer. A similar effect, but on a smaller scale, was caused also by the increase of the time of immersion in sulfuric -phosphoric acid solution. The decrease of galvanic coupling gives rise to a more homogeneous nucleation of the chromate conversion coating on the ~urface of the Alclad 2024- T3. Moreover, the chromate film tends to be denser and with fewer defects.