Amorphous silicon thin films as a high capacity anodes for Li-ion batteries in ionic liquid electrolytes

摘要

High lithiation capacity at low red-ox potentials in combination with good safety characteristics makes amorphous Si as a very promising anode material for rechargeable Li batteries. Thin film silicon electrodes were prepared by DC magnetron sputtering of silicon on stainless steel substrates. Their behavior as Li insertion/extraction electrodes was studied by voltammetry and chronopotentiometry at room temperature in the ionic liquid (IL) 1-methyl-1-propylpiperidinium bis(trifluoromethylsuphonil)imide containing 1 M Li bis(trifluoromethylsuphonil)imide. Li/Si cells containing this electrolyte showed good performance with a stable Si electrodes capacity of about 3000 mA h g(-1) and a relatively low irreversible capacity. Preliminary results on cycling Si-LiCoO2 cells using this IL electrolyte are also presented. (c) 2006 Elsevier B.V. All rights reserved.