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Geochemical Constraints on the Genesis of the Scheelite Dome Intrusion-Related Gold Deposit, Tombstone Gold Belt, Yukon, Canada

机译:加拿大育空墓碑金带白钨矿穹顶侵入相关金矿床成因的地球化学约束

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The Scheelite dome intrusion-related gold deposit, western Selwyn basin, Yukon, is hosted in hornfelsed metasedimentary strata that lie adjacent to the exposed apices of a monzogranite to quartz monzonite plutonic complex of the mid-Cretaceous Tombstone-Tungsten magmatic belt, Tintina gold province, Alaska and Yukon. A variety of mineralization styles occur throughout a 10- X 3-km east-trending corridor and include reduced Au- and W-rich skarns, Au-, W- and Ag-Pb-Zn-Sb-rich quartz tension-vein arrays, and multiphase fault veins and isolated zones of Au-rich sericite-carbonate altered rock. Integrated U-Pb SHRIMP data for magmatic zircon and Ar-Ar data for magmatic and hydrothermal biotite indicate that gold mineralization occurred within 1 to 2 m.y. of magma emplacement. Fluid inclusion, oxygen isotope, and arsenopyrite geothermometry data indicate that hydrothermal minerals formed at depths of 6 to 9 km over a temperature range from <300 deg to >550 deg C. High-temperature Au-rich skarns formed at >400 deg C, whereas vein-hosted mineralization formed at 280 deg to 380 deg C. In skarns, Au is strongly associated with enrichments of Bi, Te, W, and As, whereas a variety of Au-rich veins occur, with As-rich (type 1), and Te- and W-rich (type 2) end members. Silver-Pb-Zn-Sb veins are typically Au poor and represent the latest and lowest temperature phase in the hydrothermal paragenesis. The fluid inclusion data indicate that all mineralization styles were formed from low-salinity (S4 wt % NaCl equiv) aqueous-carbonic fluids, consistent with the composition of fluid inclusions within infilled miarolitic cavities in the intrusive rocks. However, the nonaqueous fluid was predominantly CH_4 in skarn, CO_2 in Au-Te and Au-W veins, and a fluid with roughly equal amounts of CO_2, CH_4, and N_2 in Au-As and Ag-Pb-Zn-Sb veins. Oxygen isotope data are consistent with a mineralizing fluid of predominantly magmatic origin that was variably modified to more positive delta~(18)O values during interaction with ~(18)O-enriched metasedimentary strata. Sulfur isotope data suggest two possible sources of sulfur, a magmatic source characterized by delta~(34)S values of approximately -5 to 0 per mil and sulfur from the metasedimentary country rocks characterized by more negative delta~(34)S values of approximately -15 to -10 per mil. Collectively the data indicate that gold at Scheelite Dome was deposited from a magmatic-hydrothermal system. Interaction of magmatic fluids with graphitic hornfels rocks resulted in reduction of the ore fluids, higher CH_4/CO_2 ratios, and modification of the oxygen and sulfur isotope values of the ore fluids toward those of the metasedimentary hornfels. Progressive reduction and cooling of hydrothermal fluids, in addition to phase separation in vein-hosted mineralization, were the mechanisms for gold deposition. Compared to other intrusion-related gold deposits associated with the Tombstone-Tungsten magmatic belt magmatism, exposed mineralization at Scheelite Dome is predominantly hosted by hornfelsed metasedimentary rocks. This results in more diverse mineralization styles and a greater spread of isotope and fluid inclusion data.
机译:育空地区塞文盆地西部与白垩岩穹顶侵入有关的金矿床位于锡尔金金省中白垩统-钨钨岩浆岩带中的辉长岩沉积沉积地层中,毗邻层状的辉长花岗岩与石英辉长岩复合体。 ,阿拉斯加和育空地区。在整个10-X 3公里的向东趋势走廊中,会发生各种矿化方式,包括减少的富含金和钨的矽卡岩,富含金,钨和银-铅-锌-锑的石英张力脉管阵列,富金绢云母碳酸盐蚀变岩的多相断层脉和孤立带。岩浆锆石的U-Pb SHRIMP数据和岩浆及热液黑云母的Ar-Ar数据综合表明,金矿化发生在1-2 m.y.内。岩浆的位置。流体包裹体,氧同位素和毒砂地热仪数据表明,在<300摄氏度到> 550摄氏度的温度范围内,在6至9 km的深度形成了热液矿物。在> 400摄氏度的温度下形成了富含金的高温矽卡岩,在矽卡岩中,金与Bi,Te,W和As的富集密切相关,而富金的各种矿脉发生,富As的矿床(类型1) ),以及富含Te和W的(类型2)末端成员。 Silver-Pb-Zn-Sb脉通常缺金,代表热液共生中的最新和最低温度阶段。流体包裹体数据表明,所有矿化类型都是由低盐度(S4 wt%NaCl当量)的含水碳酸盐流体形成的,与侵入岩中填充的片状孔隙中流体包裹体的成分一致。然而,非水流体在矽卡岩中主要为CH_4,在Au-Te和Au-W矿脉中主要为CO_2,在Au-As和Ag-Pb-Zn-Sb矿脉中主要为CO_2,CH_4和N_2。氧同位素数据与主要为岩浆成因的矿化流体相一致,该矿化流体在与〜(18)O富集的沉积沉积层相互作用期间被可变地修改为更正的delta〜(18)O值。硫同位素数据表明存在两种可能的硫源,一种岩浆源,其特征是δ-(34)S值约为每密耳-5至0,而来自半沉积沉积岩中的硫特征在于其负δ-(34)S值更负。每密耳-15至-10。总体而言,数据表明,白钨矿穹顶的金是从岩浆热液系统中沉积的。岩浆流体与石墨角砾岩的相互作用导致了矿液的减少,较高的CH_4 / CO_2比值,以及使矿液中的氧和硫同位素值向准沉积角的变化。除了在矿脉赋存的矿脉中进行相分离外,热液的逐步还原和冷却是金沉积的机制。与与墓碑-钨岩岩浆岩浆作用有关的其他与侵入有关的金矿床相比,白钨矿穹顶的裸露矿化主要由角质变质沉积岩主成。这导致了更多样化的矿化方式以及更大范围的同位素和流体包裹体数据的传播。

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