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A Fluid inclusion study of Au-Bearing Quartz Vein Systems in the Central and North Deboi~k I)'- of the Bendigo Gold Field, Central Victoria, Australia

机译:澳大利亚中央维多利亚本迪戈金矿区中北部和北部Deboi〜k I)'-含金石英静脉系统的流体包裹体研究

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The Central and North Deborah gold deposits, with a production of about 7 tons Au, are located in one of 15 domes in the Bendigo gold field, central Victoria, Australia, an important mesothermal lode gold province. The gold-bearing quartz vein systems are hosted predominantly by reverse faults in Lower Ordovician turbidites, which underwent lower greenschist facies metamorphism. In the Central and North Deborah mines, there are six stages of quartz veins that developed in the following sequence: (1) laminated veins, with a metal association of Au-As-Sb-Pb-Zn-Ni; (2) spurs (Au); (3) massive barren veins (main dilation stage); (4) brecciated veins, with Au-As; (5) quartz-ankerite veinlets; and (6) late, pure quartz or calcite veinlets. Of the three min-eralized vein stages (1, 2, and 4), only the first one predated or was coeval with the main deformation event, whereas stages 2 and 4 postdated the main deformation. The vein structures indicate that vein development was controlled by repeated fluctuations of fluid pressure inducing hydraulic fracturing.Fluid inclusions in vein quartz contain C-O-H fluids of variable compositions. Three main types of fluid inclusions are recognized at room temperature: type I, two-phase, primary (CH_4)_v + (H_2O)_L fluid inclusions; type II, two- or three-phase, primary-pseudosecondary (CO_2)_(v or L) + (CH_4)_(v or L) + (H_2O)_L fluid inclusions, in-cluding ha, CH_4-CO_2-H_2O, and IIb, CO_2-H_2O fluid inclusions; and type III, (H_2O)_v + (H_2O)_L fluid inclusions. Type III fluid inclusions are further divided into three groups: IIIa, primary-pseudosecondary, vapor-rich; IIIb, primary-pseudosecondary, liquid-rich; and IIIc, secondary, liquid-rich.Data from fluid inclusion distribution, microthermometry, and Raman spectroscopy indicate that fluids associated with Au mineralized quartz veins (stages 1, 2, and 4) have moderate salinity ranging from 0 to 12 wt percent NaCl equiv (modeled salinities around 7-8 wt percent NaCl equiv). These veins formatted at temperatures from 325 deg to 375 deg C, and pressures of 200 to 300 MPa, with emplacement depths of about 8 to 12 km. Fluids associated with barren quartz veins (stages 3, 5, and 6) have a low salinity of about 0 to 3 wt percent NaCl equiv (modeled salinities about 2-3 wt percent NaCl equiv) and lower temperatures. There is evidence of fluid immiscibility in all vein stages and mixing between fluids of the same souce, but differing fo_2 may also have influenced gold deposition (Cox et al., 1995).Hydrothermal ore-forming fluids responsible for gold mineralization are in the CH_2-CO_2-H_2O-NaCl system, whereas those of massive barren veins (stage 3) and veinlets (stages 5 and 6) are in the CO_2-H_2O-NaCl and H_2O-NaCl systems, respectively. The carbonic phases of type I and II fluid inclusions range from pure CH_4, through mixed CH_4 and CO_2, to pure CO_2. Gold ore-forming fluids were weakly acidic, with fo_2 estimated to have been 1025 to 10~(-25) to 10~(-37) bars, and generally above the CO_2/CH_4 and below the SO_2/H_2S buffer boundaries throughout gold mineralization. The relatively reduced mineralizing fluids are similar to those of other turbidite-hosted lode gold deposits and counterparts in volcanic-plutonic terranes.
机译:中部和北部Deborah金矿位于澳大利亚中部重要的中温矿床金矿省Bendigo金矿的15个穹顶之一,金矿产量约为7吨金。含金石英脉系统主要由下奥陶纪浊质中的反向断裂所占据,这些断裂经历了较低的绿片岩相变质作用。在中部和北部Deborah矿山中,石英脉分为六个阶段,其发育顺序如下:(1)叠层脉,具有金-砷-锑-铅-锌-镍的金属缔合; (2)马刺(Au); (3)大量贫瘠的静脉(主要扩张期); (4)角状脉,含金-砷; (5)石英-无铁矿脉; (6)晚,纯石英或方解石脉。在三个矿化静脉阶段(1、2和4)中,只有第一个阶段早于或与主要变形事件同时发生,而阶段2和4在主要变形事件之后。脉状结构表明,脉动的反复波动会导致水力压裂,从而控制了脉的发育。脉石英中的流体包裹体中含有各种成分的C-O-H流体。在室温下识别出三种主要类型的流体包裹体:I型,两相,主要(CH_4)_v +(H_2O)_L流体包裹体; II型两相或三相初级伪二次(CO_2)_(v或L)+(CH_4)_(v或L)+(H_2O)_L流体包裹体,包括ha,CH_4-CO_2-H_2O以及IIb,CO_2-H_2O流体包裹体;和类型III,(H_2O)_v +(H_2O)_L流体包裹体。 III型流体包裹体又分为三类:IIIa,一次-伪二次,富蒸气; IIIb,初级-伪次级,液体丰富;来自流体包裹体分布,显微热分析和拉曼光谱的数据表明,与金矿化石英脉相关的流体(第1、2和4级)的中度盐度为0至12 wt%NaCl当量(模拟盐度约为7-8 wt%NaCl当量)。这些脉在325到375℃的温度和200到300 MPa的压力下形成,镶嵌深度约为8到12 km。与贫瘠的石英脉相关的流体(第3、5和6阶段)的盐度较低,约为NaCl当量的0%到3%(模拟盐度约为NaCl 2-3%),并且温度较低。有证据表明流体在所有静脉阶段均不混溶,并且同一来源的流体之间混合,但是不同的fo_2也可能影响金的沉积(Cox等人,1995)。负责金矿化的热成矿流体在CH_2中。 -CO_2-H_2O-NaCl系统,而大面积的贫瘠静脉(第3阶段)和细脉(第5和第6阶段)分别位于CO_2-H_2O-NaCl和H_2O-NaCl系统中。 I型和II型流体包裹体的碳相范围从纯CH_4到混合CH_4和CO_2到纯CO_2。金矿形成液呈弱酸性,fo_2估计为1025至10〜(-25)至10〜(-37)巴,并且在整个金矿化过程中,通常在CO_2 / CH_4之上和SO_2 / H_2S缓冲边界以下。相对减少的矿化流体类似于其他浊质岩型矿床金矿床,以及火山岩-火山岩地层中的对应物。

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