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首页> 外文期刊>The Journal of Chemical Physics >Locally coupled coherent states and Herman-Kluk dynamics
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Locally coupled coherent states and Herman-Kluk dynamics

机译:局部耦合相干态和Herman-Kluk动力学

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摘要

An exact analysis of coupled coherent state (CCS) theory in the moving locally quadratic Hamiltonian approximation is shown to reproduce both the linearized coherent state matrix element of the Herman-Kluk propagator and the coherent state overlap with Heller's thawed Gaussian wave function. The derivation is applicable to anharmonic as well as harmonic system, because the quadratic approximation is taken to apply only in the vicinity of a particular classical trajectory. new compact pressions for the linearized Herman-Kluk coherent state matrix element are given, and improvements for the practical application of CCS theory are discussed.
机译:在移动局部二次哈密顿近似中对耦合相干态(CCS)理论的精确分析表明,它既可以再现Herman-Kluk传播器的线性相干态矩阵单元,也可以再现与Heller解冻高斯波函数的相干态重叠。该推导适用于非谐波和谐波系统,因为二次近似仅适用于特定经典轨迹附近。给出了线性化Herman-Kluk相干态矩阵单元的新紧压,并讨论了CCS理论实际应用的改进。

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