Non-isothermal reduction mechanism and kinetics of high chromium vanadium-titanium magnetite pellets

摘要

Non-isothermal reduction kinetics and mechanism of high chromium vanadium-titanium magnetite pellets were studied at 400-1100 degrees C, simulating the lumpy zone of blast furnace conditions. The phase transformation behaviour of valuable elements including Fe, Cr, V and Ti and microstructural changes of reduced pellets were examined by means of X-ray diffraction (XRD) and SEM-EDX. The swelling of reduced pellets was highest at 900 degrees C, while cold crushing strength was highest at 1100 degrees C. Phase transformation behaviour of valuable elements in the lumpy zone is as follows: Fe2O3 -> RFe3O4 -> RFeO -> RFe; Fe2Ti3O9 -> RFe2TiO4 -> RFe5TiO8 -> RFeTiO3; V2O3 -> RVO; (Fe0.6Cr0.4)(2)O-3 -> FeO center dot Cr2O3 -> RCr2O3. By analysing the non-isothermal reduction kinetics of high chromium vanadium-titanium magnetite pellets, based on the evaluation of reaction activation energy calculated according to Coats-Redfern method, gaseous internal diffusion through solid product layer and interfacial chemical reaction are most likely to be the main rate controlling steps in the reduction process.