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Study of complex impedance spectroscopic properties of the alpha-NaCuPO4 compound

机译:α-NaCuPO4化合物的复杂阻抗谱性质研究

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In the present study, alpha-NaCuPO4 compound was prepared by solid-state reaction method and characterized by X-ray powder diffraction and infrared spectroscopy. The AC electrical conductivity and dielectric relaxation properties of this compound have been investigated by means of impedance spectroscopy measurements over a wide range of frequencies and temperatures 209 Hz-1 MHz and 598-708 K, respectively. Both impedance and modulus analysis exhibit the grain and grain boundary contribution in the electrical response of the sample. It was found that the data of the AC measurements follow the overlapping large polaron tunneling model and the model's parameters were determined.
机译:本研究采用固相反应法制备了α-NaCuPO4化合物,并利用X射线粉末衍射和红外光谱对其进行了表征。通过阻抗谱测量,分别在209 Hz-1 MHz和598-708 K的宽频率和温度范围内研究了该化合物的交流电导率和介电弛豫特性。阻抗和模量分析都显示了晶界和晶界对样品电响应的贡献。结果表明,交流测量数据遵循重叠的大极化子隧穿模型,并确定了模型参数。

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