Synthesis, crystal structure and magnetic properties of [Cu(bipy)(2)(CH3COO)][Cu(bipy)(2)(Cr(C2O4)(3))]center dot similar to 10.5H(2)O, the first compound containing the [Cr(C2O4)(3)](3-) building block acting as a monodentate ligand

摘要

The reaction between copper(II) acetate with 2,2'-bipyridine and K-3[Cr(C2O4)(3)] leads to the novel salt [Cu(bipy)(2)(CH3COO)][Cu(bipy)(2)(Cr(C2O4)(3))]. similar to 10.5H(2)O, 1 (bipy = 2,2'-bipyridine). The crystal structure of 1 consists of mononuclear cationic species [Cu(bipy)(2)(CH3COO)](+) and heterobinuclear anionic units, [Cu(bipy)(2)(Cr(C2O4)(3))](-). The tris-oxalatochromium entity behaves as a monodentate ligand toward the copper(II) ion within the complex anion. The distance between Cr(III) and Cu(II) across the bridging oxalato group is 5.056(2) Angstrom. The copper(II) ions exhibit a distorted trigonal bipyramidal surrounding in both cationic and anionic species. The pi-pi stacking interaction between bipy ligands of the neighboring [Cu(bipy)(2)(CH3COO)](+) mononuclear entities leads to chains of copper atoms running along the b axis. Magnetic susceptibility measurements of 1 in the temperature range of 1.9-290 K reveal a quasi-Curie law behavior, the magnetic coupling between Cr(III) and Cu(II) through the bridging oxalato group with the bidentate/monodentate coordination mode being negligible. (C) 2001 Elsevier Science B.V. All rights reserved. [References: 31]