The supramolecular architecture of the second coordination sphere complex between the ammonia adduct of tris(pentafluorophenyl)borane and pyrimidine: Two interpenetrating chiral (10,3)-a (srs) nets assembled through hydrogen bonding

摘要

Treatment of the ammonia adduct of tris(pentafluorophenyl)borane with 1.5 equivalents of pyrimidine affords a crystalline supramolecular complex. The solid state structure of the chloroform solvate has been determined by X-ray crystallography and is composed of two interpenetrating chiral (10,3)-a (srs) nets assembled through N-H?N hydrogen bonding interactions.