首页> 外文期刊>International Journal of Quantum Chemistry >WHY IRREVERSIBILITY - THE FORMULATION OF CLASSICAL AND QUANTUM MECHANICS FOR NONINTEGRABLE SYSTEMS
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WHY IRREVERSIBILITY - THE FORMULATION OF CLASSICAL AND QUANTUM MECHANICS FOR NONINTEGRABLE SYSTEMS

机译:为什么不可逆性-不可积分系统的经典和量子力学公式

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摘要

Nonintegrable Poincare systems with a continuous spectrum (so-called large Poincare systems, LPS) lead to the appearance of diffusive terms in the frame of classical or quantum dynamics. These terms break time symmetry. They lead, therefore, to limitations to classical trajectory theory and of wave-function formalism (Schrodinger's equation). These diffusive terms correspond to well-defined classes of dynamical processes (i.e., so-called vacuum-vacuum transitions). The diffusive effects are amplified in situations corresponding to persistent interactions. As a result, we have to include, already, in the fundamental dynamical description the two basic aspects, probability and irreversibility, which are so conspicuous on the macroscopic level. We have to formulate both classical and quantum mechanics on the Liouville level of probability distributions (or density matrices). For integrable systems, we recover the usual formulation of classical or quantum mechanics. Instead of being primitive concepts, which cannot be further analyzed, trajectories and wave functions appear as special solutions of the Liouville-von Neumann equations. This extension of classical and quantum dynamics permits us to unify the two concepts of nature that we inherited from the nineteenth century, based, on the one hand, on dynamical time-reversible laws and, on the other, on an evolutionary view associated to entropy. It leads also to a unified formulation of quantum theory, avoiding the conventional dual structure based on Schrodinger's equation, on the one hand, and on the ''collapse'' of the wave function, on the other. A dynamical interpretation is given to processes such as decoherence or approach to equilibrium without any appeal to extra dynamic considerations (such as many-world theory, coarse graining, or averaging over the environment). There is a striking parallelism between classical and quantum theory. For large Poincare systems (LPS), we have, in general, both a ''collapse'' of trajectories and of wave functions. In both cases, we need a generalized formulation of dynamics in terms of probability distributions or density matrices. Since the beginning of this century, we have known that classical mechanics had to be generalized to take into account the existence of universal constants. We now see that classical as well as quantum mechanics also have to be extended to include unstable dynamical systems such as LPS. As a result, we achieve a new formulation of ''laws of physics'' dealing no more with certitudes but with probabilities. This formulation is appropriate to describe an open, evolving universe. (C) 1995 John Wiley and Sons, Inc. [References: 30]
机译:具有连续光谱的不可积分Poincare系统(所谓的大型Poincare系统,LPS)导致在经典或量子动力学的框架中出现扩散项。这些术语破坏了时间对称性。因此,它们导致了对经典轨迹理论和波函数形式主义(薛定inger方程)的限制。这些扩散项对应于动力学过程的明确定义的类别(即,所谓的真空-真空跃迁)。在与持续性相互作用相对应的情况下,扩散效应被放大。结果,我们必须已经在基本动力学描述中包括了两个基本方面,即概率和不可逆性,这两个方面在宏观上如此明显。我们必须在概率分布(或密度矩阵)的Liouville层次上制定经典力学和量子力学。对于可积系统,我们恢复了经典力学或量子力学的通常表述。轨迹和波动函数不再是无法进一步分析的原始概念,而是作为Liouville-von Neumann方程的特殊解决方案出现的。古典动力学和量子动力学的这种扩展使我们能够统一我们从19世纪继承的两个自然概念,一方面基于动态时间可逆定律,另一方面基于与熵相关的进化观点。它也导致了量子理论的统一表述,一方面避免了基于薛定inger方程的常规对偶结构,另一方面避免了波函数的“塌陷”。对诸如退相干或达到平衡的过程进行了动态解释,而没有任何额外的动态考虑因素(例如多世界理论,粗粒度分析或环境平均)。古典理论与量子理论之间存在惊人的相似性。通常,对于大型庞加莱系统(LPS),我们既有轨迹的“崩溃”也有波函数的“崩溃”。在这两种情况下,我们都需要根据概率分布或密度矩阵来概括动力学。从本世纪初开始,我们就知道必须对经典力学进行泛化,以考虑到普遍常数的存在。我们现在看到经典力学和量子力学也必须扩展到包括不稳定的动力学系统,例如LPS。结果,我们实现了一种新的“物理定律”表述,不再涉及确定性而是涉及概率。这种表述适合描述一个开放的,不断发展的宇宙。 (C)1995 John Wiley and Sons,Inc. [参考:30]

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