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Jade (Nephrite and Jadeitite) and Serpentinite: Metasomatic Connections

机译:玉(软玉和硬玉)和蛇纹石:交代联系

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The lapidary term "jade" refers to two very tough, virtually monomineralic rocks used for ornamental carvings or gems. Both have metasomatic origins that are intimately connected with their host serpentinite bodies and convergent-margin petrotectonics. Amphibole jade is nephrite, a trem-olite-actinolite rock with a felted, microcrystalline habit; pyroxene jade is jadeite rock (jadeilite), which varies from micro- to macrocrystalline textures. Most nephrite occurs along fault contacts between serpentinite and mafic to felsic igneous rocks or metagraywacke in obduction settings. It forms by Ca- and Si-rich, aqueous fluid-mediated metasomatic replacement of serpentinite, typically antigorite, at greenschist-facies or lower P-T conditions. Other nephrite bodies reflect contact metasomatic replacement of dolomite by Si-rich aqueous fluids during felsic pluton emplacement. Like most nephrite, jadeitite is hosted by antigorite-dominated serpentinite bodies. However, these serpentinites are associated with HP/LT metamorphic terranes, in which jadeitite occurs as isolated tabular bodies or tectonized blocks. Based on texlural evidence, particularly clear from cathodoluminescence studies, nearly all jadeitite bodies appear to have formed originally as vein crystallization of an aqueous fluid, most readily interpreted as Na-Al-Si-rich fluid at HP/LT conditions in subduction/collisional settings. The host serpentinite influences jadeitite compositions by lowering fluid a_(SiO2) during serpentinization. and contributing Ca + Mg +- Cr to late-stage jadeitite-forming fluids. Thus, although both types of jade form in convergent-margin tectonic settings, jade has two distinct primary modes of origin: (1) by siliceous replacement of already serpentinized ultramafic rock at low-P, low- to moderate-T conditions following obduction (nephrite); or (2) by the interaction of serpentinizing peridotite and Na-Al-Si fluids at HP/LT conditions during active subduction/collision (jadeitile).
机译:宝石术语“玉”是指用于装饰雕刻或宝石的两种非常坚硬的,几乎单矿物的岩石。两者的交代起源都与它们的宿主蛇纹岩体和会聚的岩石构造学密切相关。角闪石玉是软玉,斜长石-阳起石岩石,具有毡状微晶习性。辉石玉是翡翠岩(jadeilite),其质地从微晶到大晶。在缓蚀环境下,大多数软玉发生在蛇纹岩和镁铁质至长石质火成岩或变灰质瓦克之间的断层接触处。它是通过在绿片岩相或较低的P-T条件下,富含钙和硅的水流体介导的蛇纹石(通常为蛇纹石)的交代置换形成的。其他软玉体反映了在长英质质子体置入过程中,富硅水流体对白云石的接触交代替代。像大多数软玉一样,翡翠是由以蛇纹石为主的蛇纹岩体包裹的。然而,这些蛇纹岩与HP / LT变质地层有关,其中翡翠以孤立的板状体或构造块体的形式出现。根据形态学证据,尤其是从阴极荧光研究可以清楚地看出,几乎所有翡翠体似乎都是最初形成为含水流体的静脉结晶,在俯冲/碰撞环境下,很容易解释为在HP / LT条件下富含Na-Al-Si的流体。蛇纹石基质通过在蛇纹石化过程中降低流体a_(SiO2)来影响翡翠的成分。并向后期翡翠形成流体中贡献Ca + Mg +-Cr。因此,尽管两种类型的翡翠都在会聚边缘构造环境中形成,但翡翠具有两种不同的主要成因模式:(1)在低磷,低至中度T条件下,通过硅质置换已经蛇形化的超镁铁质岩块(软玉);或(2)在主动俯冲/碰撞过程中,蛇纹岩化橄榄岩和Na-Al-Si流体在HP / LT条件下的相互作用(翡翠)。

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