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Comparison of Catalytic Reforming Processes for Process Integration Opportunities: Brief Review

机译:流程整合机会的催化重整流程比较:简要回顾

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摘要

Catalytic reforming process is one of the most important processes in oil refineries that produce high octane number gasoline. Catalytic reforming processes are commonly classified into three types based on the regeneration systems of the catalyst, namely (i) semi-regenerative catalytic reformer process (SRCRP), (ii) cyclic regenerative catalytic reformer process (CRCRP) and (iii) continuous catalytic regeneration reformer process (CCRRP). The major difference among the three processes is the requirement to shut down for catalyst regeneration. The mechanism for the regeneration steps could be classified into fixed-bed catalyst system; fixed-bed catalyst combined a swing reactor and a move-bed catalyst with special regenerator of SRCRP, CRCRP or CCRRP type respectively. The CCRRP produces a higher octane reformates in the range 95-108 with a low feed quality compared to the other reactors types. Furthermore, the process produces hydrogen gas continuously at higher catalyst activity. High yield of hydrogen is also achieved at lower recycle ratio and lower operating pressure (50 psig). As the process requires continuous energy supply to maintain the optimum temperature of the reactor, simultaneous integration of mass and heat can be used as means to identify opportunities for design improvement.
机译:在生产高辛烷值汽油的炼油厂中,催化重整工艺是最重要的工艺之一。基于催化剂的再生系统,催化重整方法通常分为三种类型,即(i)半再生催化重整方法(SRCRP),(ii)循环再生催化重整方法(CRCRP)和(iii)连续催化再生重整过程(CCRRP)。这三个过程之间的主要区别是需要关闭催化剂以进行再生。再生步骤的机理可分为固定床催化剂体系。固定床催化剂分别将回转反应器和移动床催化剂与SRCRP,CRCRP或CCRRP型专用再生器结合在一起。与其他反应器类型相比,CCRRP可以在95-108范围内以较低的进料质量生产出更高的辛烷值重整产品。此外,该方法以较高的催化剂活性连续产生氢气。在较低的循环比和较低的工作压力(50 psig)下也可获得高产氢。由于该过程需要持续的能量供应以维持反应器的最佳温度,因此质量和热量的同时整合可用作确定改进设计机会的手段。

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