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Efficient Switching and Domain Interlocking Observed in Polyaxial Ferroelectrics

机译:多轴铁电体中的高效开关和域联锁

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We present transmission electron microscopy observations of domain wall motion in thin freestanding KnbO_3 crystals under applied electric fields. Since there is no substrate, there is no elastic clamping of 90 deg domains. We observe that curved and tilted 90 deg domain walls are the most mobile, whereas untilted 90 deg domain walls are resistant to field-induced motion. We explain this result in terms of two factors. First, the switching pressure on a domain wall (P_2-P_1) centre dot E is determined by the relative electrostatic energies of the neighboring polarizations P_1 and P_2. Consequently, some 90 deg domain walls are immobile under certain field directions, leading to domain interlocking. Second, do-main walls experiencing a high switching pressure move by a ripple mechanism, and do not move as rigid sheets. The tilted wall region in such a ripple has a polarization charge, and an associated depolarization field, which reduces the local switching barrier. An accumulation of polarization charge can result in a tilted or curved wall, as occurs at the mobile tips of 90 deg domain needles. Any increase in density of immobile wall configurations with cycle time represents an inherent contribution to fatigue. Uniaxial ferroelectrics, with polarizations parallel to the field, should not experience such domain interlocking.
机译:我们目前在施加电场的情况下,薄壁自立式KnbO_3晶体中畴壁运动的透射电子显微镜观察。由于没有基板,因此没有90度磁畴的弹性夹持。我们观察到弯曲和倾斜的90度磁畴壁最容易移动,而倾斜的90度磁畴壁可以抵抗磁场引起的运动。我们用两个因素来解释这个结果。首先,畴壁(P_2-P_1)中心点E上的切换压力由相邻极化P_1和P_2的相对静电能确定。因此,某些90度的畴壁在某些场方向上无法移动,从而导致畴互锁。第二,经受高切换压力的主墙通过波纹机构移动,并且不作为刚性板移动。这样的波纹中的倾斜壁区域具有极化电荷和相关的去极化场,从而减小了局部开关势垒。极化电荷的积累会导致壁倾斜或弯曲,就像在90度磁畴针的活动尖端出现的那样。固定壁结构的密度随循环时间的任何增加都代表了疲劳的固有原因。极化平行于电场的单轴铁电体不应经历这种畴互锁。

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