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首页> 外文期刊>Inorganic Chemistry Communications >Molecular structure design based on Lewis acid-base interaction in the preparation of bimetallic alkoxides derived from two electronegative elements. The synthesis and X-ray single crystal study of Mo_2Ta_4O_8(OMe)_(16) and Mo_4Ta_2O_8(O~iPr)_(14)
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Molecular structure design based on Lewis acid-base interaction in the preparation of bimetallic alkoxides derived from two electronegative elements. The synthesis and X-ray single crystal study of Mo_2Ta_4O_8(OMe)_(16) and Mo_4Ta_2O_8(O~iPr)_(14)

机译:基于路易斯酸碱相互作用的分子结构设计,用于制备由两种负电性元素衍生的双金属醇盐。 Mo_2Ta_4O_8(OMe)_(16)和Mo_4Ta_2O_8(O〜iPr)_(14)的合成及X射线单晶研究

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摘要

Complex formation between molybdenum and tantalum alkoxides has been achieved via activation of the homometallic species,both being Lewis acids, by either partial hydrolysis or partial thermolysis in hydrocarbon media. The crystal structures of the products formed, Mo_2Ta_4O_8(OMe)_(16)(Ⅰ) and Mo_4Ta_2O_8(O~iPr)_(14)(Ⅱ) respectively,are described.
机译:钼和烷氧基钽之间的络合物的形成是通过在烃介质中进行部分水解或部分热解来活化均是路易斯酸的同金属物质实现的。描述了所形成产物的晶体结构,分别为Mo_2Ta_4O_8(OMe)_(16)(Ⅰ)和Mo_4Ta_2O_8(O〜iPr)_(14)(Ⅱ)。

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