Synthesis,structures and characters of one 3D 2-fold interpenetrating net with rare 4~2 6~3 8 topology

摘要

Herein,one metallic-organic coordinated polymer,namely Cd_2(bpp)_3(mu~2-Cl)_2(mu-Cl)_2 (1) (bpp=1,3-bis(4-pyridyl)propane) was synthesized hydrothermally by the reaction of bpp ligands with CdCl_2,possessing the 3D 2-fold interpenetrating nets with the rare four-connected sra-type zeolite topology.Further,the luminescent and thermal stability characters are investigated,and the results reveal that they could to be potential,microporous and fluorescent materials.