Clicking not cooking: Functionalization of 2,2':6',2'-terpyridines by diol-boric acid interactions

Edwin C. Constable; Guoqi Zhang; Catherine E. Housecraft

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Clicking not cooking: Functionalization of 2,2':6',2'-terpyridines by diol-boric acid interactions

机译：点击不煮：通过二醇-硼酸相互作用官能化2,2'：6'，2“-吡啶

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A diol-boric acid condensation is a simple type of CLICK reaction that can be applied to give a family of related ligands. It is exemplified by the reaction of 4'-(3,4-dihydroxyphenyl)-2,2':6',2"-terpyridine with naphthalene-1-boronic acid. The single crystal structures of VMeOH and [Fe(1)2][BF4]2·4H2O·0.2CH3CN are presented.

机译：二醇-硼酸缩合是一种简单的CLICK反应类型，可用于产生一系列相关配体。以4'-（3,4-二羟基苯基）-2,2'：6'，2“-吡啶与萘-1-硼酸反应为例。VMeOH和[Fe（1）的单晶结构2]给出了[BF 4] 2·4H 2 O·0.2CH 3 CN。

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《Inorganic Chemistry Communications》 |2010年第7期|共4页
作者
Edwin C. Constable; Guoqi Zhang; Catherine E. Housecraft;
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正文语种 eng
中图分类无机化学;
关键词
2; 2':6'; 2"-Terpyridine; Boronic acid; Modular strategy; Structure;

机译：2;2'：6';2“-三联吡啶;硼酸;模块化策略;结构;

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专利

1. Clicking not cooking: Functionalization of 2,2':6',2"-terpyridines by diol-boric acid interactions [J] . Edwin C. Constable, Guoqi Zhang, Catherine E. Housecraft Inorganic Chemistry Communications . 2010,第7期

机译：点击不煮：通过二醇-硼酸相互作用官能化2,2'：6'，2“-吡啶
2. Synthesis, crystal structure, and density functional theory study of a zinc(II) complex containing terpyridine and pyridine-2,6-dicarboxylic acid ligands: Analysis of the interactions with amoxicillin [J] . Adedibu C. Tella, Joshua A. Obaleye, Margaret D. Olawale, Comptes Rendus Chimie . 2019,第1期

机译：含有吡啶和吡啶-2,6-二羧酸配体的锌（II）络合物的合成，晶体结构和密度泛函理论研究：与阿莫西林相互作用分析
3. The effect of incorporating carboxylic acid functionalities into 2,2′-bipyridine on the biological activity of the complexes formed: synthesis, structure, DNA/protein interaction, antioxidant activity and cytotoxicity [J] . Thangavel Sathiya Kamatchi, Nataraj Chitrapriya, Sarvana Loganthan Ashok Kumar, RSC Advances . 2017,第27期

机译：将羧酸官能团引入2,2'-联吡啶对形成的复合物的生物学活性的影响：合成，结构，DNA /蛋白质相互作用，抗氧化活性和细胞毒性
4. Functionalized Oligomers and Copolymers with Metal Com-plexing Segments: A Simple and High Yield Entry towards 2,2':6',2"-Terpyridine Monofunctionalized Telechelics [C] . Ulrich S. Schubert, Christian Eschbaumer Tailormade Polymers . 2001

机译：具有金属络合链段的功能化低聚物和共聚物：向2,2'：6'，2“-三联吡啶单官能化Telechelics的简单且高收率的入口
5. Synthesis and Characterization of [Ru(tpyOH)(bpy)(H2O)][OTf]2 (tpyOH = 4′-Hydroxy-2,2’:6′, 2″- Terpyridine, Bpy = 2,2′-Bipyridine) for Water Oxidation Catalysis [D] . Isaacs, Diane Pearl. 2019

机译：[Ru（TPYOH）（BPY）（H2O）] [otf] 2（TPYOH = 4'-羟基-2,2'：6'，2“ - Terpyridine，BPy = 2,2'- Bi吡啶）的合成与表征用于水氧化催化
6. catena-Poly[[(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ2O:O′] [O] . Hai-Yan Gong, Yan Bai, Wei Liu 2016

机译：阳离子多聚体[[（（2,2'：6'，2''-特吡啶-κ3N，N'，N''）锌（II）]-μ-2,2'-氧二苯并-κ2O：O′]
7. Copper(ii) complexes of functionalized 2,2′:6′,2′′-terpyridines and 2,6-di(thiazol-2-yl)pyridine: structure, spectroscopy, cytotoxicity and catalytic activity [O] . Katarzyna Czerwińska, Barbara Machura, Slawomir Kula, 2017

机译：铜（II）官能化2,2'：6'，2' - 三吡啶和2,6-二（噻唑-2-基）吡啶：结构，光谱，细胞毒性和催化活性

Clicking not cooking: Functionalization of 2,2':6',2'-terpyridines by diol-boric acid interactions

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