Deactivation mechanism of SO2 on Cu/SAPO-34 NH3-SCR catalysts: structure and active Cu2+

摘要

The deactivation mechanism of Cu/SAPO-34 ammonia selective catalytic reduction catalysts (NH3-SCR) by SO2 poisoning has been systematically investigated using a range of analytical techniques in order to study the influence on both the zeolitic framework and the active Cu2+ ions. The different sulfate samples were obtained by SO2 poisoning over Cu/SAPO-34 NH3-SCR catalysts as a function of time and concentration in the feed. The obtained results reveal that the SO2 poisoning could seriously decrease NO conversion during the whole temperature range (100-500 degrees C). The XRF results shows that there is almost no sulfur existing on the SAPO-34 support. The ex situ DRIFTS and BET results reveal that SO2 poisoning has a less-pronounced effect on its framework structure. The TPR and EPR results demonstrate that SO2 poisoning has a significant influence on the coordination environment and the content of the active isolated Cu2+ species. The kinetic results demonstrate that the SO2 poisoning does not influence the apparent activation energy (Ea) of the NH3-SCR reaction over Cu/SAPO-34 catalysts. The decline of the NH3-SCR activity is due to the reduction of the number of isolated Cu2+ ions.