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首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >In-situ-generation of alkylsilyl peroxides from alkyl hydroperoxides and their subsequent copper-catalyzed functionalization with organosilicon compounds
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In-situ-generation of alkylsilyl peroxides from alkyl hydroperoxides and their subsequent copper-catalyzed functionalization with organosilicon compounds

机译:用有机硅化合物原位产生来自烷基氢过氧化物的烷基甲硅烷基甲硅烷基甲硅烷基过氧化物及其随后的有机硅化合物的铜催化官能化

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摘要

Alkylsilyl peroxides were generated in situ from the corresponding alkyl hydroperoxides using organosilicon compounds of the type Me3SiX (X = CN, N-3, and halogens) and an amine base. Subsequent in situ copper-catalyzed homolytic cleavage of the alkylsilyl peroxides afforded alkyl radicals, which were then trapped with X (X = CN, N-3, and halogens) to furnish products with new carbon-carbon, carbon-nitrogen, or carbon-halogen bonds in good to high yields. (C) 2021 Elsevier Ltd. All rights reserved.
机译:使用Me3SiX型有机硅化合物(X=CN、N-3和卤素)和胺基,从相应的烷基氢过氧化物原位生成烷基硅基过氧化物。随后,铜催化的烷基硅过氧化物的原位均裂裂解产生烷基自由基,然后用X(X=CN,N-3和卤素)捕获烷基自由基,以高到高的产率提供具有新碳-碳、碳-氮或碳-卤素键的产物。(c)2021爱思唯尔有限公司保留所有权利。

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