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Synthesis and characterization of bromophenol blue encapsulated silica and silica-titania nanocomposites for detection of volatile organic vapors

机译:溴苯酚蓝封装二氧化硅和二氧化硅 - 二氧化钛纳米复合材料的合成与表征检测挥发性有机蒸汽

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摘要

Owing to pH sensing applications in the food industry, bromophenol blue immobilized silica (BPB-S) and silicatitania (BPB-ST) nanocomposites are synthesized by the sol-gel route. Fundamental analysis confirms that both nanomatrices have porous surface and thermal stability at >= 400 C. Evanescent wave absorption-based fiber optic pH sensors are prepared by coating of BPB-S and BPB-ST nanocomposites. when the evanescent field interacts with the sensing coating, absorption varied due to pH change and the output intensity is recorded as a sensor response. The sensitivity of the BPB-S and BPB-ST nanocomposite is calculated as -136.65 counts/pH and - 17.95 counts/pH, respectively. The BPB-ST nano-matrix exhibited a fast response 0.2 s than BPB-S nanocomposite response 0.8 s. The fish's freshness is determined visually by assessing the change in the color against the fish pH. The findings confirm that synthesized nanocomposites have the potential to detect volatile organic vapors in terms of pH.
机译:由于pH传感在食品工业中的应用,采用溶胶-凝胶法合成了溴酚蓝固定化二氧化硅(BPB-S)和硅钛氧化物(BPB-ST)纳米复合材料。基础分析证实,这两种纳米基质在>=400℃时都具有多孔表面和热稳定性。通过涂覆BPB-S和BPB-ST纳米复合材料,制备了基于倏逝波吸收的光纤pH传感器。当倏逝场与传感涂层相互作用时,吸收因pH变化而变化,输出强度记录为传感器响应。BPB-S和BPB-ST纳米复合材料的灵敏度计算分别为-136.65计数/pH和-17.95计数/pH。BPB-ST纳米基质的响应速度为0.2秒,而BPB-s纳米复合材料的响应速度为0.8秒。通过评估鱼的pH值对颜色的变化,目视确定鱼的新鲜度。研究结果证实,合成的纳米复合材料具有检测pH值方面挥发性有机蒸汽的潜力。

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