Performance and mechanism of chelating resin (TP-207) supported Pd/Cu bimetallic nanoparticles in selective reduction of nitrate by using ZVI (zero valent iron) as reductant

摘要

In the present study, a Pd/Cu bimetallic catalyst supported on a chelating resin (TP207) was prepared in order to selectively reduce nitrate to N2 with ZVI (zero valent iron) as a reductant. The effects of Pd/Cu mass ratio, temperature, and initial solution pH on the removal of nitrate and TN were then examined. The highest nitrate (63.2%) removal was obtained under neutral conditions at a ratio of Pd/Cu 2:1, in which 57.8% of TN was removed and N2 accounted for more than 90% of the final products. Additional ammonia (30-40%) were formed when the reaction was conducted at a higher temperature (313 K) compared to when performed at 303 K. The mechanism study for nitrate reduction indicated that this catalyst could broaden the suitable pH range and improve the selectivity of N2 without the generation of other intermediate compounds or by-products in comparison to ZVI and its combination with a non-supported Pd/Cu catalyst. The slow rate of ZVI corrosion, high Fe (II) proportion in corrosion products and high N/H ratio at neutral pH conditions may serve as reasons for the high N2 selectivity. The chelating resin also played a key role via its load capacity and dispersion ability to Pd/Cu particles in enhancing N2 selectivity. Accordingly, the proposed method may have great potential application for nitrate reduction to N2, which warrants further study.