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Study of the influence of melamine polyphosphate and aluminum hydroxide on the flame propagation and explosion overpressure of aluminum magnesium alloy dust

机译:三聚氰胺多磷酸盐和氢氧化铝对铝镁合金粉尘火焰繁殖和爆炸超压的影响研究

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摘要

When aluminum magnesium alloy dust floats in the air, a certain ignition energy can easily cause an accidental explosion. To prevent and control the occurrence of accidental explosions and reduce the severity of accidents, it is necessary to carry out research on the explosion suppression of aluminum magnesium alloy dust. This paper uses a vertical glass tube experimental device and a 20 L spherical explosive experimental device to carry out experimental studies on the suppression of the flame propagation and explosion overpressure of aluminum magnesium alloy dust with melamine polyphosphate (MPP) and Al(OH)(3). With increasing MPP and Al(OH)(3) concentrations, the flame brightness darkened, the flame velocity and propagation distance gradually decreased, and P-max and (dp/dt)(max) decreased significantly. When the amount of MPP added reached 60%, the flame propagation distance decreased to 188 mm, which is a decrease of 68%, and the explosion overpressure decreased to 0.014 MPa, effectively suppressing the explosion of aluminum magnesium alloy dust. The experimental results showed that MPP was more effective than Al(OH)(3) in inhibiting the flame propagation and explosion overpressure of the aluminum magnesium alloy dust. Finally, the inhibitory mechanisms of the MPP and Al(OH)(3) were further investigated. The MPP and Al(OH)(3) endothermic decomposition produced an inert gas, diluted the oxygen concentration and trapped active radicals to terminate the combustion chain reaction.
机译:当铝镁合金粉尘漂浮在空气中时,一定的点火能量很容易引起意外爆炸。为了预防和控制意外爆炸的发生,降低事故的严重性,有必要开展铝镁合金粉尘抑爆研究。本文采用垂直玻璃管实验装置和20L球形炸药实验装置,对三聚氰胺聚磷酸盐(MPP)和氢氧化铝(OH)(3)抑制铝镁合金粉尘火焰传播和爆炸超压进行了实验研究。随着MPP和Al(OH)(3)浓度的增加,火焰亮度变暗,火焰速度和传播距离逐渐减小,P-max和(dp/dt)(max)显著降低。当MPP加入量达到60%时,火焰传播距离减小到188mm,降低了68%,爆炸超压降低到0.014MPa,有效地抑制了铝镁合金粉尘的爆炸。实验结果表明,MPP比Al(OH)(3)对铝镁合金粉尘的火焰传播和爆炸超压有更有效的抑制作用。最后,进一步研究了MPP和Al(OH)(3)的抑制机制。MPP和Al(OH)(3)吸热分解产生惰性气体,稀释氧浓度并捕获活性自由基以终止燃烧链式反应。

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