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Protective Aftereffect of IFKhAN-92 Inhibitor for Corrosion of Nickel-Chromium Steel in Hydrochloric Acid

机译:IFKhan-92抑制剂的保护性 - 盐酸镍铬钢腐蚀

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摘要

It is shown that the multimolecular protective layer of an organic inhibitor formed on the surface of chromium-nickel steel in an HCl solution containing a triazole derivative, the inhibitor IFKhAN-92, has a protective aftereffect in background solutions of the same acid. Such a protective layer is chemically bonded to the Fe, Cr, and Ni oxide and hydroxide phase adjacent to the metal phase. The lower part of the polymolecular protective layer of the organic inhibitor consists of a polymer complex formed by IFKhAN-92 molecules, metal cations (Fe, Cr, and Ni), and chloride anions, and the outer part consists of physically adsorbed IFKhAN-92 molecules, which are easily removed from the metal surface during ultrasonic washing of samples.
机译:研究表明,在含有三唑衍生物的盐酸溶液中,铬镍钢表面形成的有机抑制剂IFKhAN-92的多分子保护层在相同酸的背景溶液中具有保护后效。这种保护层通过化学方式与金属相附近的铁、铬、镍氧化物和氢氧化物相结合。有机抑制剂的多分子保护层的下部由IFKhAN-92分子、金属阳离子(Fe、Cr和Ni)和氯离子形成的聚合物络合物组成,外部由物理吸附的IFKhAN-92分子组成,这些分子在样品超声波清洗过程中很容易从金属表面去除。

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