Synthesis and Properties of Metal Phthalocyanines Containing Anthraquinone Chromophores

摘要

Nucleophilic substitution of bromine in 4-bromophthalonitrile gave anthraquinone-substituted nitriles, sodium 2-{[4-(3,4-dicyanophenoxy)-9,10-dioxo-9,10-dihydroanthracen-1-yl]amino}-5-methylbenzenesulfonate and 4-[(2-hydroxy-9,10-dioxo-9,10-dihydroanthracen-1-yl)oxy]phthalonitrile, which were used to obtain the corresponding cobalt phthalocyanines by the nitrile method.