Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels

Sergey A. Lermontov; Alena N. Malkova; Nataliya A. Sipyagina; Alexey V. Semakov; Alexander E. Baranchikov; Vladimir K. Ivanov

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Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels

机译：三氟甲酸甲酯 - 一种用于生产氟化有机间苯二酚 - 甲醛气凝胶的新溶剂

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Resorcinol–formaldehyde aerogels obtained in methyl trifluoropyruvate (MTFP) possess a fluorinated matrix due to the mechanism of electrophilic substitution in the resorcinol moiety with the formation of C–C bond. The use of MTFP as a solvent also substantially accelerates the formaldehyde– resorcinol interaction.

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《Mendeleev Communications 》 |2018年第1期| 共3页
作者
Sergey A. Lermontov; Alena N. Malkova; Nataliya A. Sipyagina; Alexey V. Semakov; Alexander E. Baranchikov; Vladimir K. Ivanov;
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Institute of Physiologically Active Compounds Russian Academy of Sciences;

Institute of Physiologically Active Compounds Russian Academy of Sciences;

Institute of Physiologically Active Compounds Russian Academy of Sciences;

Institute of Physiologically Active Compounds Russian Academy of Sciences;

N. S. Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciences;

N. S. Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciences;

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正文语种 eng
中图分类化学 ;
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Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels

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