Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels

Sergey A. Lermontov; Alena N. Malkova; Nataliya A. Sipyagina; Alexey V. Semakov; Alexander E. Baranchikov; Vladimir K. Ivanov

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Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels

机译：三氟甲酸甲酯 - 一种用于生产氟化有机间苯二酚 - 甲醛气凝胶的新溶剂

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Resorcinol–formaldehyde aerogels obtained in methyl trifluoropyruvate (MTFP) possess a fluorinated matrix due to the mechanism of electrophilic substitution in the resorcinol moiety with the formation of C–C bond. The use of MTFP as a solvent also substantially accelerates the formaldehyde– resorcinol interaction.

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显示省略在三氟甲酸甲酯（MTFP）中获得的间苯二酚 - 甲醛气凝胶具有氟化基质，因为电泳的机制具有氟化基质将间苯二酚部分取代与形成C-C键。使用MTFP作为溶剂也基本上加速了甲醛 - 间苯二酚相互作用。 ]]>

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《Mendeleev Communications 》 |2018年第1期| 共3页
作者
Sergey A. Lermontov; Alena N. Malkova; Nataliya A. Sipyagina; Alexey V. Semakov; Alexander E. Baranchikov; Vladimir K. Ivanov;
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Institute of Physiologically Active Compounds Russian Academy of Sciences;

Institute of Physiologically Active Compounds Russian Academy of Sciences;

Institute of Physiologically Active Compounds Russian Academy of Sciences;

Institute of Physiologically Active Compounds Russian Academy of Sciences;

N. S. Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciences;

N. S. Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciences;

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中图分类化学 ;
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1. Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels [J] . Sergey A. Lermontov, Alena N. Malkova, Nataliya A. Sipyagina, Mendeleev Communications . 2018 ,第1期

机译：三氟甲酸甲酯 - 一种用于生产氟化有机间苯二酚 - 甲醛气凝胶的新溶剂
2. Synthesis and Characterization of Resorcinol-Formaldehyde Organic Aerogel [J] . Sun Young Kim, Dong Ho Yeo, Jae Woo Lim Journal of Chemical Engineering of Japan . 2001 ,第2期

机译：间苯二酚-甲醛有机气凝胶的合成与表征
3. Synthesis and Characterization of Resorcinol-Formaldehyde Organic Aerogel [J] . DONG HO YEO, HWAYONG KIM, JAE WOO LIM, Journal of Chemical Engineering of Japan . 2001 ,第2期

机译：间苯二酚-甲醛有机气凝胶的合成与表征
4. EFFECTS OF ORGANIC SOLVENT ON THE PORE STRUCTURE OF RESORCINOL-FORMALDEHYDE - BASED CARBON AEROGELS [C] . Alain Celzard, Andrzej Szczurek, Gisele Amaral Annual World Conference on Carbon . 2011

机译：有机溶剂对间苯甲醛 - 甲醛碳气凝胶孔隙结构的影响
5. Shear Performance of Southern Pine Glued Orthogonally with Phenol-resorcinol-formaldehyde or Polyurethane [D] . Cao, Guangmei. 2018

机译：苯酚-间苯二酚-甲醛或聚氨酯正交粘合的南方松的剪切性能
6. Water-Ionic Liquid Binary Mixture Tailored Resorcinol-Formaldehyde Carbon Aerogels without Added Catalyst [O] . Balázs Nagy, István Bakos, Erik Geissler, 2019

机译：不添加催化剂的水离子液体二元混合物量身定制的间苯二酚-甲醛碳气凝胶
7. Data for the synthesis of resorcinol–formaldehyde aerogels in acidic and basic media [O] . Daniel F. Molina-Campos, Rafael A. Fonseca-Correa, Diana P. Vargas-Delgadillo, 2017

机译：在酸性和碱性介质中合成间苯二酚 - 甲醛气凝胶的数据

Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels

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