New Mechanism for Depositing Platinum, Palladium, and Rhodium on Iron Metal Collector

摘要

The effect of using an iron metal collector (MC) instead of copper on the degree of extraction of platinum, palladium, and rhodium is investigated in processing ceramic-based automotive catalysts in an electric arc furnace. The dependence of the effect of melt holding time on platinum group metal (PGM) deposition rate on a furnace hearth is analyzed. It is determined that during creation of a homogeneous mixture and introducing a metal collector (MC) into the catalyst composition effective Pt, Pd, Rh extraction occurs in the first 20 minutes of melt exposure. In spite of the twice as high density of platinum, the degree of its extraction is at the level for Pd and Rh, which points to the possibility of depositing platinum group metals (PGM) on the furnace hearth using the surface of coarser added MC powder. Testing of various methods for adding MC demonstrate the effectiveness of introduction to the melt surface. When a melt is heated above the melting temperature of platinum and palladium, the maximum degree of extraction is reached in 6 min. This shows that solid rhodium may passivate the surface of added MC. In order to create conditions when there is always an MC free surface to which solid rhodium may adhere, the rate coefficient is determined for effective dissolution of Rh in iron MC. Determination of this coefficient makes it possible to scale up results of laboratory studies and to predict the minimum time required for melting MC on the furnace hearth without loss of valuable component.