A review on conductometric studies of electrolytes in mixed solvent systems to understand ion-ion and ion-solvent interactions

摘要

The study of ion-solvent interaction is of much importance to investigate the nature of different solutions. Measurement of electrical conductivity and evaluation of physico-chemical properties, such as molar conductance, limiting molar conductance, ion-pair association, Walden product etc. shade light on different intermolecular interactions present in electrolyte solutions. Solvation properties can be varied by mixing two or more solvents. An extensive literature survey on conductometric studies has been carried out on different electrolytes dissolved in a wide range of mixed solvent systems. The reported results show that strong solute-solute, solute-solvent and olvent-solvent interactions are responsible for the physico-chemical behavior of a solution in mixed solvents.