首页> 外文期刊>Journal of Applied Polymer Science >Effect of silane treated fly ash on physico-mechanical, morphological, and thermal properties of recycled poly(vinyl chloride) composites
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Effect of silane treated fly ash on physico-mechanical, morphological, and thermal properties of recycled poly(vinyl chloride) composites

机译:硅烷处理的粉煤灰对再生(氯乙烯)复合材料的物理机械,形态学和热性能的影响

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The silane treatment on properties of fly ash (FA) and development of its composite using recycled poly(vinyl chloride) (r-PVC) material retrieve from waste wires and cable insulation are investigated in this work. The use of (3-aminopropyl)triethoxysilane was employed as a coupling agent with some other essential additives. The composites sheet was prepared by means of the melt mixing process and go along with the compression molding process. The superior properties on compatibility between silane-modified FA (FA(Si)) and r-PVC were successfully studied using rheological, thermomechanical, morphological, and water absorption analysis. Primary analysis of r-PVC and FA was employed using Fourier transform infrared spectroscopy analysis. The thermal stability of composites was stable up to 187 degrees C. In addition, significant enhancement on tensile strength as well as young's modulus of composite as compared to untreated r-PVC/FA composites. Morphological properties of silane treated FA based composites presented the good distribution and excellent uniformity with higher wettability of FA particles within r-PVC matrix. The water absorption test showed decrease in water absorption with increase silane treatment concentration FA in the r-PVC matrix. It was remarkable to note that silane treated FA can be prepared as a composite using r-PVC matrix with further modified properties.
机译:本文研究了硅烷处理对粉煤灰(FA)性能的影响,以及利用从废电线和电缆绝缘中回收的回收聚氯乙烯(r-PVC)材料开发粉煤灰复合材料。使用(3-氨基丙基)三乙氧基硅烷作为偶联剂与其他一些必需添加剂。该复合材料片材是通过熔融混合工艺和压缩成型工艺制备的。通过流变学、热机械、形态和吸水性分析,成功地研究了硅烷改性FA(FA(Si))与r-PVC之间的优异相容性。采用傅里叶变换红外光谱法对r-PVC和FA进行初步分析。复合材料的热稳定性在187℃时保持稳定。此外,与未经处理的r-PVC/FA复合材料相比,复合材料的拉伸强度和杨氏模量显著提高。硅烷处理后的FA基复合材料具有良好的分散性和均匀性,且FA颗粒在r-PVC基体中具有较高的润湿性。吸水率测试表明,随着r-PVC基质中硅烷处理浓度FA的增加,吸水率降低。值得注意的是,经硅烷处理的FA可以使用具有进一步改性性能的r-PVC基质作为复合材料制备。

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