A feasible process for removal and utilization of CO2 in thermal power plants by MDEA plus DMSO scrubbing and Cu/TiO2 photocatalytic reduction

摘要

A dynamic system for simultaneous removal of CO2/SO2/NOx and desorption of CO2 was developed using N-methyl diethanolamine and dimethyl sulfoxide (MDEA + DMSO) scrubbing. The equilibrium of the absorption-desorption system was achieved as the CO2 absorption rate was approximately equal to the CO2 desorption rate. Then the Cu/TiO2 catalysts under different calcination temperature or with different Cu weight percent were prepared using the modified sol-gel method. Their crystal structures, morphologies, and pore properties were characterized by powder X-ray diffraction, scanning electron microscope, and nitrogen adsorption. The 2 wt% Cu/TiO2 under the calcination temperature of 500 degrees C exhibits the highest activity for photoreduction of CO2 into CH3OH with the CH3OH yield of 12.35 mu mol/g/h at 363 K, owing to its smallest crystal size, highest BET surface area and lowest recombination of photogenerated electrons and holes. Meanwhile, a feasible process for the removal and photoreduction of CO2 in thermal power plants using MDEA + DMSO scrubbing and Cu/TiO2 photocatalytic reduction was proposed basing on experimental results. As most of the energy consumption is supplied by solar energy, the process is economical, energy-saving and environmentally friendly.