Enhanced Thermometric Sensor for Arsenate Analysis Based on Dual Temperature Readout Signaling Strategy

摘要

New methods for portable detection of arsenate are still in urgent need. Herein, we explored a simple but sensitive thermometric strategy for arsenate determination without complex instruments and skilled technicians. Cobalt oxyhydroxide (CoOOH) nanoflakes, can ingeniously decompose hydrogen peroxide into oxygen in a sealed reaction vessel, accompanied by marked pressure and significant temperature increase due to the exothermic reaction effect (Delta H = -98.2 kJ/mol). The increased pressure then compelled a certain amount of H2O overflowing from the drainage device into another vessel, leading to a significant temperature decrease due to the preloaded ammonium nitrate (NH4NO3) and its good dissolution endothermic effect (Delta H = 25.4 kJ/mol). In the presence of arsenate, the catalytic activity of CoOOH nanoflakes for H2O2 decomposition was inhibited dramatically, resulting in an obvious decrease of the pressure, weighting water and temperature response. The two temperature responses with increasing and decreasing feature were easily measured through a common thermometer, and exhibited an effective signaling amplification via coupling both "signal-on" and "signal-off" temperature readout elements. The obtained dual superimposing temperature readout exhibits a good linear with the concentration of arsenate with a lower detection limit (51 nM, 3.8 ppb). Compared to the inductively coupled plasma mass spectrometry, this enhanced thermometric strategy provides a simple, rapid, convenient, low cost, and portable platform for sensing arsenate in real environmental water.