Sensitized Two-NIR-Photon Z -> E Isomerization of a Visible-Light-Addressable Bistable Azobenzene Derivative

Moreno Javier; Gerecke Mario; Grubert Lutz; Kovalenko Sergey A.; Hecht Stefan

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Sensitized Two-NIR-Photon Z -> E Isomerization of a Visible-Light-Addressable Bistable Azobenzene Derivative

机译：敏化的双尼尔 - 光子Z - > E异构化可见光可寻料双稳态偶氮衍生物

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摘要

Two-NIR-photon-triggered Z -> E isomerization of an azobenzene was accomplished by covalently linking a two-photon-harvesting triarylamine antenna to a thermally stable ortho-fluorinated azobenzene derivative. The obtained photo-switch is fully addressable with visible and NIR light by using one-photon and two-photon excitation, respectively, with the latter offering enhanced penetration depth and improved spatial resolution.

机译：通过将双光子收获三芳基胺天线共价连接到热稳定的邻氟化偶氮苯衍生物，实现二氮苯的二丙基 - 光子触发的Z - > E异构化。通过使用单光子和双光子激发，所获得的光交换机可通过可见光和NIR光，后者提供增强的穿透深度和改善的空间分辨率。

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来源
《Angewandte Chemie》 |2016年第4期|共4页
作者
Moreno Javier; Gerecke Mario; Grubert Lutz; Kovalenko Sergey A.; Hecht Stefan;
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作者单位

Humboldt Univ Dept Chem Brook Taylor Str 2 D-12489 Berlin Germany;

Humboldt Univ Dept Chem Brook Taylor Str 2 D-12489 Berlin Germany;

Humboldt Univ Dept Chem Brook Taylor Str 2 D-12489 Berlin Germany;

Humboldt Univ Dept Chem Brook Taylor Str 2 D-12489 Berlin Germany;

Humboldt Univ Dept Chem Brook Taylor Str 2 D-12489 Berlin Germany;

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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
azobenzenes; energy transfer; near infrared; photochromism; two-photon photochemistry;

机译：偶氮苯;能量转移;近红外;光致变色;双光子光化学;

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1. Sensitized Two-NIR-Photon Z -> E Isomerization of a Visible-Light-Addressable Bistable Azobenzene Derivative [J] . Moreno Javier, Gerecke Mario, Grubert Lutz, Angewandte Chemie . 2016,第4期

机译：敏化的双尼尔 - 光子Z - > E异构化可见光可寻料双稳态偶氮衍生物
2. Theoretical study of the isomerization mechanism of azobenzene and disubstituted azobenzene derivatives [J] . Crecca CR, Roitberg AE The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2006,第26期

机译：偶氮苯与二取代偶氮苯衍生物异构化机理的理论研究
3. An Optimized Glutamate Receptor Photoswitch with Sensitized Azobenzene Isomerization [J] . Gascon-Moya Marta, Pejoan Arnau, Izquierdo-Serra Merce, The Journal of Organic Chemistry . 2015,第20期

机译：具有敏化偶氮苯异构化的优化谷氨酸受体光电开关
4. Effect of the Introduction of a CF_3 Group to a Silyl-Anchor Azobenzene Dye on Sensitization Property in Dye-Sensitized Solar Cells [C] . Kenji Kakiage, Takuro Abe, Masaki Yamamura International Conference on Advanced Micro-Device Engineering . 2016

机译：将CF_3组引入染色致敏性太阳能电池致敏性质的含有硅烷基锚偶氮苯染料的影响
5. New protein structure prediction method using inter-residue distances and a theoretical investigation of the isomerization of azobenzene and disubstituted azobenzenes. [D] . Crecca, Christina R. 2008

机译：一种新的利用残基间距离预测蛋白质结构的方法以及对偶氮苯和二取代的偶氮苯异构化的理论研究。
6. ComputationalDesign and Synthesis of a Deeply Red-Shiftedand Bistable Azobenzene [O] . David B. Konrad, Gökcen Savasci, Lars Allmendinger, -1

机译：计算的深红移的设计与合成和双稳态偶氮苯
7. Quantum Chemical Investigation of Thermal Cis-to-Trans Isomerization of Azobenzene Derivatives: Substituent Effects, Solvent Effects, and Comparison to Experimental Data [O] . Marcel Gothe, Jonas Wirth, Maike V. Peters, 2015

机译：偶氮苯衍生物的热顺式 - 反式异构化的量子化学研究：取代基效应，溶剂效应和与实验数据的比较
8. Cis/Trans Isomerization in Azobenzene - Chain Liposomes [R] . Moss, R. A., Jiang, W. 1995

机译：偶氮苯链脂质体中的顺式/反式异构化

Sensitized Two-NIR-Photon Z -> E Isomerization of a Visible-Light-Addressable Bistable Azobenzene Derivative

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