Laponite-Based Surfaces with Holistic Self-Cleaning Functionality by Combining Antistatics and Omniphobicity

摘要

In the present work, perfluoroalkylated laponite nanoparticles with a high degree of functionalization (60 wt %) have been prepared and a methodology to prepare transparent, antistatic, and omniphobic laponite-based films with holistic self-cleaning properties against liquids, solids and liquid solid mixtures has been developed. The intrinsic electrical and ionic conductivities observed in unmodified laponite coatings are combined with perfluoroalkyl-modified laponite clays. As a result, films with improved self-cleaning functionality based on dust-repellency and omniphobic liquid-repellence (sheet resistance in the range of 10(7) Omega/square and contact angles of 106 degrees(H2O) and 93 degrees (oil)) were obtained. These unique films, being capable to repel dust and liquids, were applied to a variety of substrates (i.e., glass and plastics) and tested against solids and liquids of different nature with excellent performance. Bending tests of these holistic self-cleaning films deposited over flexible substrates showed better mechanical performance than unmodified laponite films.