Study on iron-based adsorbents for alternating removal of H2S and O-2 from natural gas and biogas

摘要

This study deals with the development of iron oxide/hydroxide adsorbents for the alternating removal of H2S and O-2 from natural gas and biogas. The considered procedure initially implies the chemisorption of H2S. In the second step, O-2 is removed by reaction with the H2S-treated substrate accompanied by regeneration of the adsorbent. 35 different iron-based samples were physical-chemically characterized and tested towards H2S/O-2 break through behavior and adsorption capacity to evaluate structure-performance correlations. It was derived that high BET surface area, high proportion of meso and micro pores, small average pore diameter, low crystallinity and high number of Bronsted acid sites are crucial properties of the adsorbents. As a consequence, Fe (OH)(3) and alpha-FeOOH revealed highest efficiency for the successive adsorption of H2S and O-2, while alpha-Fe2O3 provided rather low performance.