Unravelling the role of dual quantum dots cocatalyst in 0D/2D heterojunction photocatalyst for promoting photocatalytic organic pollutant degradation

摘要

Hydrogen peroxide (H2O2) was generally considered as an ideal energy carrier and environment-friendly oxidant to process environmental modification. Here, FeOOH QDs and CQDs was interspersed on g-C3N4 ultrathin nanosheet to promote H2O2 generation and in-situ decomposition. FeOOH QDs/CQDs/g-C3N4 composite (FCCN) exhibited excellent photoactivity for degrading oxytetracycline (OTC) under visible light illumination. The accelerated photoactivity is ascribed to the following merits: 1) the exciton dissociation interface and carrier transfer channel are fabricated to facilitate photoexcited electron transfer; 2) the photoexcited electron can be rapidly utilized by molecular oxygen to generate H2O2, resulting in facilitated molecular oxygen activation; 3) Fe3+ in FeOOH QDs is reduced to Fe2+ by photoexcited electron, and then reacts with generated H2O2 to produce center dot OH, thereby promoting photodegradation efficiency. The H2O2 generation yield of FCCN-2 composite was 224.24 mu mol h(-1) g(-1), which was higher than that of pure g-C3N4. 3,3',5,5'-tetramethylbenzidine (TMB) oxidation and center dot O-2(-) quantitative determination displayed outstanding molecular oxygen activation capacity of hybrid composite. Moreover, 0D/2D heterojunction photocatalyst displayed weakened charge carrier recombination efficiency (0.0015 s-1) and expedited surface carrier transfer efficiency (41.01%) compared to gC(3)N(4) and CQDs/g-C3N4 photocatalyst. Finally, the photodegradation mechanism were rationally evaluated based on the experiment results.