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A new process for simultaneous nitrogen removal and phosphorus recovery using an anammox expanded bed reactor

机译:使用厌氧膨胀床反应器进行同时氮去除和磷恢复的新方法

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摘要

Phosphorus recovery from wastewater is an important approach for sustainable phosphorus use. In this work, a process combining anammox and hydroxyapatite (HAP) precipitation in an expanded bed reactor for simultaneous nitrogen removal and phosphorus recovery was developed by applying specific Ca/P ratio and pH control. A high phosphorus removal rate (0.14?±?0.01?kg-P/m3/d) was obtained while a stable nitrogen removal efficiency (87.4?±?2.9%) maintained with an effluent recirculation system applied. Average 13.4% phosphorus (30.7% in P2O5) accumulation in the dry sludge and a Ca/P ratio very close to HAP was observed by quantitative elemental analysis. In this work, different analysis revealed the two layers structure with anammox biofilm attached to inorganic core of the granules. Different spectral analysis determined the major phase of the inorganic content as hydroxyapatite. With proper Ca/P ratio and pH control, anammox expanded bed reactor was transformed into an efficient process to simultaneously remove nitrogen and recover phosphorus.
机译:废水中的磷恢复是可持续磷使用的重要方法。在这项工作中,通过施加特异性Ca / P比率和pH控制,开发了一种用于同时氮气去除和磷回收的膨胀床反应器中厌氧和羟基磷灰石(HAP)沉淀的方法。获得高磷去除速率(0.14?±0.01 kg-p / m3 / d),而施用稳定的氮去除效率(87.4〜±2.9%),采用施用的污水再循环系统。通过定量元素分析观察到平均13.4%的磷(P2O5中的30.7%)在干污泥中积聚和非常接近Hap的Ca / P比率。在这项工作中,不同的分析揭示了与颗粒的无机核附着的anammox biofilm两层结构。不同的光谱分析确定了无机含量的主要阶段作为羟基磷灰石。通过适当的Ca / P比和pH控制,将厌氧膨胀床反应器转化为有效的方法,以同时除去氮并回收磷。

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