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Synthesis of Amorphous FeOOH/Reduced Graphene Oxide Composite by Infrared Irradiation and Its Superior Lithium Storage Performance

机译:红外辐射法合成非晶态FeOOH /氧化石墨烯及其优异的储锂性能

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摘要

A new hybrid nanostructure composed of mildly reduced graphene oxide (mRGO) nanosheets and homogeneous loading of amorphous FeOOH with ultrafine particles (~2 nm) is successfully synthesized via a facile infrared irradiation approach. Surprisingly, the as-prepared FeOOH/mRGO hybrid exhibits high reversible capacity, long-term stability, and excellent rate performance, when used as an anode material for lithium-ion batteries. A high reversible capacity of 767 mA h g~(-1) , with a coulombic efficiency of ~100%, can be achieved at a high current density of 1000 mA g~(-1) even after 600 discharge/charge cycles. The superior electrochemical performances are attributed to the synergistic effects of the small particle size, amorphous structure, and conductive mRGO.
机译:通过轻柔的红外辐射方法成功地合成了由轻度还原的氧化石墨烯(mRGO)纳米片和均匀的无定形FeOOH与超细颗粒(〜2 nm)组成的新型杂化纳米结构。出人意料的是,当用作锂离子电池的负极材料时,所制备的FeOOH / mRGO混合动力电池具有高可逆容量,长期稳定性和出色的倍率性能。即使在600次放电/充电循环后,在1000 mA g〜(-1)的高电流密度下也可以实现767 mA h g〜(-1)的高可逆容量,库仑效率约为100%。优异的电化学性能归因于小粒径,无定形结构和导电mRGO的协同作用。

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