Silica Nanoparticle Doped Organic Ionic Plastic Crystal Electrolytes for Highly Efficient Solid-State Dye-Sensitized Solar Cells

摘要

Organic ionic plastic crystal, 1-propyl-1-meth-ylpyrrolidinium iodide (P^l), which possesses a broad plastic phase from -36 to 135 °C, was doped with silica nanoparticles (SiO2 NPs) and 1-ethyl-3-methylimidazolium iodide (EMU), for the preparation of SiO2/EMII/P_(13)I solid-state electrolytes for dye-sensitized solar cells (DSSCs). The thermal properties of all the electrolytes, including solid-solid phase transitions and melting temperatures, were investigated by differential scanning calorimetry (DSC). The effect of silica particles on the ionic conductivity, diffusion of I~-/I3~- redox couple in electrolytes, and photovoltaic performance for solid-state DSSCs were investigated. The fabricated solid-state DSSCs yielded a high power conversion efficiency of 5.25% under simulated air mass 1.5 solar spectrum illuminations at 50 mW cm~(-2). Furthermore, the DSSCs based on SiO2/EMII/P_(13)I solid-state electrolytes show good stability after an accelerating aging test, demonstrating potential practical applications.