Applications of in Situ Raman Spectroscopy for Identifying Nickel Hydroxide Materials and Surface Layers during Chemical Aging

摘要

The applications of in situ vibrational spectroscopy for identifying bulk and surface Ni(OH)2 are discussed. Raman spectra from α- and β-Ni(OH)2 samples immersed in water are generally similar to those collected from comparable dry samples. However, the Raman scattering intensities vary, and dry β-Ni(OH)2 additionally exhibits a surface O-H stretching mode at 3690 cm~(-1). Using in situ Raman spectroscopy, the spontaneous transformation of α-Ni(OH)2 to β-Ni(OH)2 in room-temperature water was monitored. Such transformations are conventionally performed in high-temperature alkaline media. An intralayer OH-diflusion model is proposed. Internal stresses at the α/β-phase boundary caused shifted peaks, higher order vibrational modes, and a new water peak at 3520 cm~(-1). We conclude that Raman spectroscopy may be applied to observe Ni(OH)2 materials in situ during chemical and electrochemical treatments. Such measurements provide information on the proportions of α- and β-Ni(OH)2 and their fine structural details with high sensitivity.