Estimation of breaking off possibility of radical-chain reaction by primary radicals

N. A. Mukhitdinova; V. O. Kudyshkin; M. A. Askarov

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Estimation of breaking off possibility of radical-chain reaction by primary radicals

机译：估计主要基本自由基自由基反应的可能性

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摘要

A kinetic model of initiation of radical-chain processes in the presence of allylic monomers has been deduced for a first time. Its application to copolymerization of aminoalkylmethacrylates and allylglycidilic ether allowed to get a quantitative estimation of primary radicals part that taking in chain breaking off reaction.

机译：首次推导出在烯丙基单体存在下激进的基链过程的动力学模型。其施用于氨基烷基甲基丙烯酸盐和烯丙基丙基乙基醚的共聚，使初级自由基部分的定量估计，所述主要自由基部分接受断裂反应。

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《Доклады Академии Наук Республики Узбекистан》 |1998年第7期|共4页
作者
N. A. Mukhitdinova; V. O. Kudyshkin; M. A. Askarov;
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angeaSystems.com;

angeaSystems.com;

angeaSystems.com;

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原文格式 PDF
正文语种 rus
中图分类自然科学总论;
关键词
radical-chain reaction; primary radicals; model; aminoalkylmethacrylates and allylglycidilic;

机译：激进的反应;主要自由基;模型;氨基烷基甲基丙烯酸酯和烯丙基丙烯酸酯;

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1. Estimation of breaking off possibility of radical-chain reaction by primary radicals [J] . N. A. Mukhitdinova, V. O. Kudyshkin, M. A. Askarov Доклады Академии Наук Республики Узбекистан . 1998,第7期

机译：估计主要基本自由基自由基反应的可能性
2. Vicinal alkylation-carboxymethylation of electron-poor alkenes by radical-chain reactions with O-alkyl O-silyl ketene acetals and their [3+2]annulation by reaction with O-cyclopropylcarbinyl O-silyl ketene acetals [J] . Yudong Cai, Brian P.Roberts Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2004,第7期

机译：贫电子烯烃的邻位烷基化-羧甲基化，通过与O-烷基O-甲硅烷基烯酮缩醛的自由基链反应和[3 + 2]环化反应与O-环丙基羰基O-甲硅烷基烯酮缩醛反应
3. Visible light/Ir(III) photocatalytic initiation of xanthate-based radical-chain reactions: Xanthate group transfer and oxidative addition to aromatic systems [J] . Lopez-Mendoza Pedro, Diaz John E., Loaiza Alix E., Tetrahedron . 2018,第38期

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4. Mathematical modeling of radical-chain reaction of isopropylbenzene oxidation [C] . M K Vovdenko, E A Ahmerov, K F Koledina, International Conference on Information Technology and Nanotechnology . 2020

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5. Kinetics Studies of Two Free Radicals, Amidogen Radical and Allyl Radical: Amidogen Radical(A2A1) Emission Lifetimes in the (0,9,0) and (0,8,0) Bands and Allyl Radical Reactions With Nitrogen Dioxide, Methyl Radical and Allyl Radical. [D] . N'Doumi, Marc. 2012

机译：两种自由基的动力学研究：酰胺基自由基和烯丙基自由基：（0,9,0）和（0,8,0）谱带中的酰胺基自由基（A2A1）发射寿命以及二氧化氮，甲基自由基和烯丙基的烯丙基自由基反应基。
6. Breaking the Light and Heavy Chain Linkage of Human Immunoglobulin G1 (IgG1) by Radical Reactions [O] . Boxu Yan, Daniel Boyd 2011

机译：通过自由基反应破坏人免疫球蛋白G1（IgG1）的轻链和重链连接
7. Proton-coupled electron transfer: a unifying mechanism for biological charge transport, amino acid radical initiation and propagation, and bond making/breaking reactions of water and oxygen [O] . Chang Christopher J., Chang Michelle C.Y., Damrauer Niels H., 2004

机译：质子耦合电子转移：生物电荷传输，氨基酸自由基引发和传播以及水和氧的键形成/断裂反应的统一机制
8. Studies of the energetics of C-S bond-breaking reactions in radical ions derived from coal model compounds. Final report, January 1, 1989-August 31, 1990. [R] . Bausch, M. J. 1990

机译：煤模型化合物自由基离子中C-s键断裂反应的能量学研究。最终报告，1989年1月1日至1990年8月31日。

Estimation of breaking off possibility of radical-chain reaction by primary radicals

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